MINATO Makoto

Affiliation

Faculty of Engineering, Division of Materials Science and Chemical Engineering

Job Title

Associate Professor

Research Fields, Keywords

Organometallics, Organic Synthesis



Education 【 display / non-display

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    1989

    Tokyo Institute of Technology   Completed

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    1989

    Tokyo Institute of Technology   Chemical Engineering   Doctor Course   Completed

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    1981

    Waseda University   Graduated

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    1981

    Waseda University   Applied Chemistry   Graduated

Degree 【 display / non-display

  • Doctor of Engineering - Tokyo Institute of Technology

Campus Career 【 display / non-display

  • 2007.4
     
     

    Duty   Yokohama National UniversityFaculty of Engineering   Division of Materials Science and Chemical Engineering   Associate Professor  

  • 2001.4
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    2007.3

    Duty   Yokohama National UniversityFaculty of Engineering   Division of Materials Science and Chemical Engineering   Associate Professor  

  • 1997.10
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    2001.3

    Duty   Yokohama National UniversitySchool of Engineering   Associate Professor  

  • 1992.7
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    1997.9

    Duty   Yokohama National UniversitySchool of Engineering   Research Assistant  

  • 1991.2
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    1992.7

    Duty   Yokohama National UniversitySchool of Engineering   Academic Affairs Staff  

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Academic Society Affiliations 【 display / non-display

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    日本化学会

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    近畿化学工業界

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    The Society of Synthetic Organic Chemistry, Japan

Research Areas 【 display / non-display

  • Life Science / Bioorganic chemistry

  • Nanotechnology/Materials / Structural organic chemistry and physical organic chemistry

 

Research Career 【 display / non-display

  • 有機金属化学

    Project Year:

  • Synthesis of novel organometallic compound. Its application to catalyst and new materials.

    Project Year:

Books 【 display / non-display

  • 第5版実験化学講座21有機遷移金属化合物超分子錯体

    ( Role: Joint author)

    丸善 

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    Language:Japanese Book type:Scholarly book

  • Science of Synthesis

    ( Role: Joint author)

    Houben-Weyl 

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    Language:English Book type:Scholarly book

Thesis for a degree 【 display / non-display

  • 金属錯体をメディエータとする電極反応の有機合成への応用

    湊 盟

    1993.3

    Doctoral Thesis   Single Work  

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    東京工業大学大学院理工学研究科化学工学専攻

    Pd,Os、Bi、などの遷移金属錯体をメディエータとする電極酸化及び還元反応の有機合成への応用を検討した。

  • 電解発生カルバニオンとπ−アリルパラジウム錯体の求核置換反応

    湊 盟

    1989.3

    Master Thesis   Single Work  

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    東京工業大学大学院総合理工学研究科電子化学専攻

    電極反応によって発生させた活性メチレンカルバニオンとπ−アリルパラジウム錯体の求核置換反応の検討

Papers 【 display / non-display

  • Allylic Alkylation Catalyzed by Molybdenum Complexes Containing Polydentate Phosphinoalkyl-Silyl Ligands

    MAKOTO MINATO, NAOTO WADA, TAKEFUMI KATSUREN, HIROAKI SHU

    Jxiv   2022.4  [Reviewed]

    DOI

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    Language:English   Publishing type:Research paper (scientific journal)   Publisher:科学技術振興機構   Joint Work  

  • One-pot synthesis of polysiloxanes using catalytic reaction of dihydroorganosilanes with DMF: A new approach to functional polysiloxanes

    Makoto Minato, Hiroshi Watanabe, Takahiro Shimizu, Takito Shibuya, Riko Yamamoto, Ken Ishikura, Da- … Show more authors

    Journal of Organometallic Chemistry   928   121550-1 - 121550-7   2020.12  [Reviewed]

    DOI

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    Language:English   Publishing type:Research paper (scientific journal)   Publisher:Elsevier   Joint Work  

  • Reactions of 1-Alkynes with a Molybdenum-Silyl Complex: Stable sigma-Acetylide Complexes Containing a Pentadentate Ligand Comprised of a P2SiP2 Framework

    Minato Makoto, Watanabe Kyosuke, Maeda Kengo

    CHEMISTRY LETTERS   48 ( 12 )   1526 - 1528   2019.12  [Reviewed]

    DOI Web of Science

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    Language:English   Publishing type:Research paper (scientific journal)   Publisher:公益社団法人 日本化学会   Joint Work  

    <p>Reactions of molybdenum-silyl hydrido complex <b>2</b> ([MoH<sub>3</sub>{Si(Ph)[Ph<sub>2</sub>PCH<sub>2</sub>CH<sub>2</sub>P(Ph)C<sub>6</sub>H<sub>4</sub>-<i>o</i>]<sub>2</sub>}]) with 1.5 equiv of 1-alkynes RC≡CH occur readily at room temperature giving σ-acetylide complexes ([MoH<sub>2</sub>{Si(Ph)[Ph<sub>2</sub>PCH<sub>2</sub>CH<sub>2</sub>P(Ph)C<sub>6</sub>H<sub>4</sub>-<i>o</i>]<sub>2</sub>}(C≡CR)]: R = Ph (<b>3a</b>), <i>t</i>-Bu (<b>3b</b>)), in which the acetylide ligands ligate at the site opposite to the Si atom.</p>

    Other Link: https://ci.nii.ac.jp/naid/130007757503

  • Formation of Metal-coordinated Doubly Chelating Pentadentate Ligands by the Reactions of [MoH4(Ph2PCH2CH2PPh2)2] with Organohydrodisilanes

    Makoto Minato,Toshiki Nanami,Kenzi Kogoma,Takashi Ito

    Chemistry Letters List Issues   47 ( 9 )   1105 - 1107   2018  [Reviewed]

    DOI

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    Language:English   Publishing type:Research paper (scientific journal)   Joint Work  

  • Research on Physical Property Evaluation of Polysilanes for Use of UV-Curing Inks

    Morikawa Noriyuki, Minato Makoto

    Journal of Printing Science and Technology   53 ( 6 )   490 - 497   2016.12  [Reviewed]

    DOI

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    Language:Japanese   Publishing type:Research paper (scientific journal)   Joint Work  

    Other Link: https://www.jstage.jst.go.jp/article/nig/53/6/53_490/_article/-char/ja/

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Review Papers 【 display / non-display

  • Molybdocenes and tungstenocenes derived from molybdenum(IV) and tungsten(IV) dihydride

    Coordination Chemistry Reviews   ( 252 )   1613 - 1629   2008.5

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    Language:English   Publishing type:Article, review, commentary, editorial, etc. (scientific journal)   Joint Work  

Awards 【 display / non-display

  • 論文賞

    2019.2   日本印刷学会   ポリシランを用いた UV 硬化型インキの硬化挙動に関する研究

    Individual or group name of awards:湊 盟

Grant-in-Aid for Scientific Research 【 display / non-display

  • Synthesis of functional polysiloxanes using molybdenum-catalyst

    2017.4 - 2019.3

    Grant-in-Aid for Scientific Research  Grant-in-Aid for Scientific Research(C)

    Investigator(s):Minato Makoto

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    Grant type:Competitive

    Using silyl-molybdenum complexes in conjunction with DMF (Me2NCHO), dihydroorganosilanes (R1R2SiH2) can be converted catalytically to polysiloxanes (-(R1R2SiO)n-). In the reactions, DMF plays a dual role of a solvent and more importantly as the oxygen source. The addition of fluoride compounds (TBAF (( n-C4H9)4NF) or KF) as a cocatalyst has been found to enhance
    the molecular weight of the resulting polysiloxanes. Since the reactions proceed under mild
    conditions, a variety of dihydroorganosilanes bearing sensitive functional groups such as amino,
    methoxycarbonyl, perfluorophenyl, ferrocenylalkyl, and (-)-menthyl groups, were amenable to our
    protocol. The present one-step procedure is an efficient method for synthesis of functional
    polysiloxanes that are highly modified.

Preferred joint research theme 【 display / non-display

  • Development of organometallic catalyst

 

Charge of on-campus class subject 【 display / non-display

  • 2022   Organometallic chemistry

    Graduate school of Engineering Science

  • 2022   Organometallic Chemistry

    College of Engineering Science

  • 2022   Inorganic Chemistry 2

    College of Engineering Science

  • 2022   Chemistry, Chemical Engineering and Life Science: Exercise A

    College of Engineering Science

  • 2022   Chemistry of Inter-element Linkage

    Graduate school of Engineering Science

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Committee Memberships 【 display / non-display

  • 社団法人近畿化学協会通常総会

    2005.4 - 2007.3  代議委員

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    Committee type:Other 

Social Contribution(Extension lecture) 【 display / non-display

  • 第51回有機金属化学討論会

    社団法人近畿化学協会  東京  2004.10

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    Type:Lecture

    Synthesis of Calix[4]arene-based Molybdenocene: Its Behavior toward Protonic Acids