MITSUSHIMA Shigenori

Affiliation

Faculty of Engineering, Division of Materials Science and Chemical Engineering

Job Title

Professor

Date of Birth

1963

Research Fields, Keywords

Industrial Electrolysis, Material, Electrolyte, Electrocatalyst, Fuel Cell

Mail Address

E-mail address

Related SDGs




写真a

Education 【 display / non-display

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    1989

    Yokohama National University   Department of Material Engineering   Master Course   Completed

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    1987

    Yokohama National University   Department of Material Chemistry   Graduated

Degree 【 display / non-display

  • Doctor in Engineering - Yokohama National University

Campus Career 【 display / non-display

  • 2011.1
     
     

    Duty   Yokohama National UniversityFaculty of Engineering   Division of Materials Science and Chemical Engineering   Professor  

  • 2007.4
    -
    2010.12

    Duty   Yokohama National UniversityFaculty of Engineering   Division of Materials Science and Chemical Engineering   Associate Professor  

  • 2006.10
    -
    2007.3

    Duty   Yokohama National UniversityFaculty of Engineering   Division of Materials Science and Chemical Engineering   Associate Professor  

  • 2001.4
    -
    2006.9

    Duty   Yokohama National UniversityFaculty of Engineering   Division of Materials Science and Chemical Engineering   Research Assistant  

  • 2000.6
    -
    2001.3

    Duty   Yokohama National UniversitySchool of Engineering   Research Assistant  

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External Career 【 display / non-display

  • 2003.8
    -
    2004.7

    Ecole Polytechnique de Montreal   Invited Researcher  

  • 1994.9
    -
    2000.5

    Hitachi Research Laboratory, Hitachi Ltd   Researcher  

  • 1989.4
    -
    1994.9

    Hitachi Research Laboratory, Hitachi Ltd  

Academic Society Affiliations 【 display / non-display

  • 2000.10
     
     
     

    The Hydrogen Energy System Society of Japan

  • 1996.3
     
     
     

    The Electrochemical Society

  • 1987.1
     
     
     

    The Electrochemical Society of Japan

Research Areas 【 display / non-display

  • Nanotechnology/Materials / Inorganic materials and properties

  • Nanotechnology/Materials / Inorganic compounds and inorganic materials chemistry

  • Manufacturing Technology (Mechanical Engineering, Electrical and Electronic Engineering, Chemical Engineering) / Chemical reaction and process system engineering

  • Manufacturing Technology (Mechanical Engineering, Electrical and Electronic Engineering, Chemical Engineering) / Electron device and electronic equipment

 

Research Career 【 display / non-display

  • 有機ハイドライド電解合成

    The Other Research Programs  

    Project Year: 2013.4

  • アルカリ水電解用アノード

    The Other Research Programs  

    Project Year: 2011.4

  • New Material for Molten Carbonate Fuel Cells

    New Sunshine Program New Sunshine Project  

    Project Year:

  • Design of the Pseudo-3D Interface for Electrochemical Energy Conversion

    JST Basic Research Programs (Core Research for Evolutional Science and Technology :CREST)  

    Project Year:

  • Material and Electrochemical Reaction for Mesothermal Fuel Cells

    New Sunshine Program New Sunshine Project  

    Project Year:

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Books 【 display / non-display

  • Processes for Production and Utilization of Organic Hydride and Ammonia

    Shigenori Mitsushima, Kensaku Nagasawa( Role: Sole author)

    ( ISBN:978-4-7813-1600-0

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    Total pages:344   Responsible for pages:27-35   Language:Japanese Book type:Scholarly book

  • Metal Oxide-Based Nanostructured Electrocatalysts for Fuel Cells, Electrolyzers, and Metal-air Batteries

    Yoshiyuki Kuroda, Shigenori Mitsushima( Role: Joint author ,  4 - Oxygen evolution reaction (OER) at nanostructured metal oxide electrocatalysts in water electrolyzers)

    Elsevier  ( ISBN:978-0-12-818496-7

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    Total pages:268   Responsible for pages:61-82   Language:English Book type:Scholarly book

  • 水素エネルギーの事典

    光島重徳 外( Role: Contributor)

    水素エネルギー協会 編  ( ISBN:978-4-254-14106-1

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    Total pages:240   Language:Japanese Book type:Scholarly book

  • Fuel Cells and Hydrogen

    Viktor Hacker, Shigenori Mitsushima( Role: Joint author)

    From Fundamentals to Applied Research 

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    Total pages:296   Language:English Book type:Scholarly book

  • リスク共生学

    ( Role: Contributor)

    丸善出版 

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    Language:Japanese Book type:Scholarly book

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Thesis for a degree 【 display / non-display

  • Fundamental study for the improvement of molten carbonate fuel cells

    Shigenori Mitsushima

    1998.12

    Doctoral Thesis   Single Work  

  • 溶融炭酸塩中における材料の劣化に関する研究

    光島重徳

    1989.3

    Master Thesis   Single Work  

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    横浜国立大学工学研究科
    溶融炭酸塩形燃料電池用のカソード材料の安定性向上を目的とし、代表的なカソード材料である酸化ニッケルの溶解度の溶融炭酸塩の組成や温度に対する依存性ならびに代替材料であるニッケルフェライトの溶解度を測定し、その溶解メカニズムを明らかにした。

Papers 【 display / non-display

  • Catalytic activity of zirconia on zirconium for the oxygen evolution reaction in potassium hydroxide

    Koichi Matsuzawa, Akimitsu Ishihara, Ayaka Oishi, Shigenori Mitsushima, Ken-ichiro Ota

    Materials Science & Engineering B   267   115112-1 - 115112-6   2021.3  [Reviewed]

    DOI

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    Language:English   Publishing type:Research paper (scientific journal)   Publisher:Elsevier   Joint Work  

    It has been reported that the Ni anode electrode used in alkaline water electrolysis (AWE) is degraded when the fluctuating electricity produced by renewable energy (wind and solar power) systems is used. To develop alternative materials, we focused on zirconium oxide because of its high chemical stability, and investigated its catalytic activity for the oxygen evolution reaction (OER) on zirconium oxides on a zirconium plate fabricated by both air oxidation (ZrO2/Zr) and arc-plasma deposition (ZrO2/Zr_APD). From cross-sectional observations and electrochemical results, the mixed tetragonal and monoclinic structure of ZrO2 was related to its catalytic activity for the OER. ZrO2/Zr_APD showed obviously a higher activity than ZrO2/Zr. The reason for this is that the particles are better dispersed in ZrO2/Zr_APD than in ZrO2/Zr, so the electrochemical surface area of ZrO2/ Zr_APD seems to be larger than that of ZrO2/Zr.
    1.

  • Control of surface area and conductivity of niobium-added titanium oxides as durable supports for cathode of polymer electrolyte fuel cells

    Yongbing Ma, Takaaki Nagai, Yuta Inoue, Kaoru Ikegami, Yoshiyuki Kuroda, Koichi Matsuzawa, Teko W. … Show more authors

    Materials and Design journal   203   109623-1 - 109632-10   2021.3  [Reviewed]

    DOI

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    Language:English   Publishing type:Research paper (scientific journal)   Publisher:Elsevier   Joint Work  

    Niobium-added titaniumoxide is a promising candidate as a substitute carbon support for cathodes ofPEFCs. Nb- added TiO2 can act as a support for platinum nanoparticles to enhance the oxygen reduction reaction (ORR) ac- tivity and durability under acidic conditions. Nb-added TiO2 supports with the desired surface area (10–130 m2 g−1) and conductivity (10−7–10−2 Scm−1) were prepared by changing the amount of Nb and the heat treatment conditions. First, we conducted a systematic investigation with changes in theamount ofniobium addition, heat-treatment temperature, and time under a pure hydrogen atmosphere to reveal the physicochem- ical factors that govern the surface area and conductivity. Finally, we successfully proposed a procedure to pre- pare highly durable Nb-added TiO2 supports with the desired surface area and conductivity by controlling the amount of niobium addition, heat-treatment temperature, and time under hydrogen. The charges of the double layer were almost unchanged after 5000 cycles of an accelerated durability test (ADT).

  • Practical and Reliable Methanol Concentration Sensor for Direct Methanol Fuel Cells

    ANDOH Shinsuke, FUJITA Akira, MIITSU Takeshi, KURODA Yoshiyuki, MITSUSHIMA Shigenori

    Electrochemistry   2021.2  [Reviewed]

    DOI CiNii

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    Language:English   Publishing type:Research paper (scientific journal)   Publisher:公益社団法人 電気化学会   Joint Work  

    An electrochemical methanol concentration sensor with practicality and reliability has been developed to apply for a direct methanol fuel cell (DMFC) system. The methanol concentration can be estimated simply by the original algorithm based on the Arrhenius law and diffusion limiting current, even though the complex oxidation current characteristics for the methanol concentration and temperature. The oxidation current of methanol shows linearity against the methanol concentration up to 10 wt% (15 mgPt cm<sup>−2</sup> at anode) with quick response. The sensor also has a high durability for 6500 h in the simulated DMFC operating temperature.

    Other Link: https://ci.nii.ac.jp/naid/130007988368

  • A New Accelerated Durability Test Protocol for Water Oxidation Electrocatalysts of Renewable Energy Powered Alkaline Water Electrolyzers

    Abdel Haleem Ashraf, Nagasawa Kensaku, Kuroda Yoshiyuki, Nishiki Yoshinori, Zaenal Awaludin, Mitsus … Show more authors

    ELECTROCHEMISTRY   89 ( 2 )   186 - 191   2021.1  [Reviewed]

    DOI Web of Science CiNii

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    Language:English   Publishing type:Research paper (scientific journal)   Publisher:公益社団法人 電気化学会   Joint Work  

    <p>For electrocatalysts of oxygen evolution reaction (OER), a new accelerated durability test (ADT) protocol is presented. The protocol is designed to closely mimic the fluctuations of renewable energies. The unit cycle of the current ADT protocol represents the "ON/OFF" operation mode. In the "ON" step, the electrolyzer operates under a DC current of 0.6 A cm<sup>−2</sup>. In the "OFF" step, the electrocatalyst is subjected to a constant potential that is clearly more cathodic than its OER onset potential (namely, 0.3, 0.5, and 0.7 V vs. RHE) for 10 or 60 s. The transition from the "ON" state to the "OFF" state occurs through a cathodic linear sweep voltammetry of a fast sweep rate to mimic the sudden changes in the renewable power. A NiCoO<i><sub>x</sub></i>/Ni-mesh electrode was used as a case study. The electrode showed remarkable durability under continuous operation (<i>i</i> = 0.6 A cm<sup>−2</sup>) for about 900 hours. However, it did suffer severe degradation after a certain number of ADT cycles, and the rate of degradation mainly depends on the potential value and the duration of the "OFF" step. Interestingly, the inclusion of the 10-sec open-circuit potential step after the "ON" step clearly mitigates the impact of energy fluctuations on the durability of OER electrocatalysts.</p>

    Other Link: https://ci.nii.ac.jp/naid/130007995096

  • The Effect of Cation Mixing in LiNiO2 toward the Oxygen Evolution Reaction

    Ren Yadan, Yamaguchi Ryusei, Uchiyama Tomoki, Orikasa Yuki, Watanabe Toshiki, Yamamoto Kentaro, Mat … Show more authors

    CHEMELECTROCHEM   8 ( 1 )   70 - 76   2021.1  [Reviewed]

    DOI Web of Science

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    Language:English   Publishing type:Research paper (scientific journal)   Publisher:Wiley   Joint Work  

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Review Papers 【 display / non-display

  • 水電解による水素製造の現状と展望

    光島 重徳、藤田 礁

    電気化学および工業物理化学   85 ( 1 )   28 - 33   2016.12

    DOI

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    Language:Japanese   Publishing type:Article, review, commentary, editorial, etc. (bulletin of university, research institution)   Publisher:電気化学会   Joint Work  

  • 固体高分子電解質(SPE)電解技術を応用した有機ハイドライド電解合成

    光島 重徳、長澤 兼作

    触媒   58 ( 6 )   346 - 350   2016.6

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    Language:Japanese   Publishing type:Article, review, commentary, editorial, etc. (scientific journal)   Publisher:触媒学会   Joint Work  

  • Present technologies and subjects of water electrolysis

    Journal of the hydrogen energy system society of Japan   36 ( 1 )   11 - 16   2011.1

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    Language:Japanese   Publishing type:Article, review, commentary, editorial, etc. (scientific journal)   Publisher:Hydrogen energy system society of Japan   Joint Work  

  • 電気化学:測定と解析のてびき 電解関連分野での応用-工業電解

    電気化学   75 ( 12 )   992 - 996   2007.12

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    Language:Japanese   Publishing type:Article, review, commentary, editorial, etc. (scientific journal)   Single Work  

  • プロトン伝導性常温溶融塩の燃料電池への応用

    工藤憲治, 太田健一郎

    燃料電池   4 ( 1 )   34 - 38   2004.7

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    Language:Japanese   Publishing type:Article, review, commentary, editorial, etc. (other)   Joint Work  

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Industrial Property Rights 【 display / non-display

  • 電解用電極及びその製造方法

    光島 重徳,黒田 義之,永島 郁男,谷口 達也,錦 善則,加藤 昭博,ジャエナル アワルディン,辻井 文哉,中井 貴章

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    Applicant:デノラ・ペルメレック株式会社,国立大学法人横浜国立大学,川崎重工業株式会社

    Application no:特願2020-505004  Date applied:2019.3.4

    Announcement no:WO2019/172160  Date announced:2019.9.12

    Country of applicant:Domestic  

  • 金属多孔体

    奥野 一樹,東野 孝浩,俵山 博匡,真嶋 正利,増村 春輝,黒田 義之,光島 重徳

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    Applicant:国立大学法人横浜国立大学,住友電気工業株式会社

    Application no:特願2020-502040  Date applied:2018.12.6

    Announcement no:WO2019/163256  Date announced:2019.8.29

    Country of applicant:Domestic  

  • アルカリ水電解用電極の評価方法、アルカリ水電解用電極の製造方法、及びアルカリ水電解用電極

    新納 英明,光島 重徳,黒田 義之,藤井 雄一

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    Applicant:旭化成株式会社,国立大学法人横浜国立大学

    Application no:特願2018-216489  Date applied:2018.11.19

    Announcement no:特開2019-143235  Date announced:2019.8.29

    Country of applicant:Domestic  

  • 酸化物分散金属多孔体、電解用電極および水素製造装置

    奥野 一樹,真嶋 正利,東野 孝浩,俵山 博匡,光島 重徳

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    Applicant:国立大学法人横浜国立大学,住友電気工業株式会社

    Application no:特願2019-514491  Date applied:2018.4.23

    Announcement no:WO2018/199025  Date announced:2018.11.1

    Country of applicant:Domestic  

  • 電極用担体材料及びその製造方法、電極材料、電極、並びに固体高分子形燃料電池

    石原 顕光,馬 永炳,光島 重徳,松澤 幸一,黒田 義之

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    Applicant:国立大学法人横浜国立大学

    Application no:特願2017-201181  Date applied:2017.10.17

    Announcement no:特開2019-075305  Date announced:2019.5.16

    Country of applicant:Domestic  

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Awards 【 display / non-display

  • 平成31年度電気化学会論文賞

    2019.3   電気化学会   Dependence of the Reverse Current on the Surface of Electrode Placed on a Bipolar Plate in an Alkaline Water Electrolyzer

    Individual or group name of awards: 内野 陽介、小林 貴之、長谷 川 伸司、永島 郁男、砂田 良 雄、真鍋 明義、錦 善則、光島 重徳

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    電気化学会H31年度論文賞 内野 陽介、小林 貴之、長谷 川 伸司、永島 郁男、砂田 良 雄、真鍋 明義、錦 善則、光島 重徳(旭化成(株)、横浜国 大、川崎重工業 (株)、ティッセンク ルップ・ウーデ・クロリ ンエンジニアズ、デノ ラ・ペルメレック)

  • 平成26年度業績賞

    2014.11   電気化学会電解科学技術委員会  

    Individual or group name of awards: 光島重徳

  • 平成25年度溶融塩賞

    2014.1   電気化学会溶融塩委員会  

    Individual or group name of awards: 光島重徳

  • 平成21年度電気化学会論文賞

    2009.3   電気化学会  

    Individual or group name of awards: 多田、青木、光島

  • 平成18年度電気化学会論文賞

    2006.4   電気化学会  

    Individual or group name of awards: 工藤、光島ほか

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Other external funds procured 【 display / non-display

  • アルカリ水電解及び固体高分子形水電解の高度化

    2018.7

    水素利用等先導研究開発事業/水電解水素製造技術高度化のための基盤技術研究開発

  • 有機ハイドライド電解合成用電極触媒の研究開発

    2017.5 - 2018.2

    エネルギー・環境新技術先導プログラム

    Investigator(s):光島重徳

  • <エネルギーキャリア・チーム>有機ハイドライド

    2013.7 - 2014.6

    Japan Science and Technology Agency  戦略的創造研究推進事業 先端的低炭素化技術開発(ALCA) 特別重点技術領域

    Investigator(s):光島重徳

Presentations 【 display / non-display

  • PEFC用 Nbドープ TiOxカソード触媒のナノ粒子化と電子伝導パス形成による半導体特性への影響検討

    足立 吉徳、永井 崇昭、大城 善郎、黒田 義之、松澤 幸一、今西 哲士、原 賢二、光島 重徳、石原顕光

    第40回水素エネルギー協会大会  (Web) 

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    Event date: 2020.12

    Language:Japanese   Presentation type:Oral presentation (general)  

    Venue:Web  

  • トルエン直接電解水素化カソード触媒層におけるマクロ構造の改善

    杉田雄也、長澤兼作、黒田義之、光島重徳

    第40回水素エネルギー協会大会  (東京) 

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    Event date: 2020.12

    Language:Japanese   Presentation type:Oral presentation (general)  

    Venue:東京  

  • Ca-Mn系四重極ペロブスカイト型酸化物の局所構造と酸素発生触媒特性

    柏原 浩大、内山 智貴、任 亜丹、山岸 弘奈、折笠 有基、渡邊 稔樹、山本 健太郎、松永 利之、光島重徳、内本 喜晴

    第44回電解技術討論会-ソーダ工業技術討論会-  (Web) 

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    Event date: 2020.11

    Language:Japanese   Presentation type:Oral presentation (general)  

    Venue:Web  

  • ハイブリッドナノシートからなるアルカリ水電解アノード用自己修復触媒の高活性化

    高津正平、谷口達也、大石 彩加、永島 郁男、猪股 昭彦、錦 善則、Zaenal Awaludin、中井 貴章、加藤 昭博、光島 重徳、黒田 義之

    第44回電解技術討論会-ソーダ工業技術討論会-  (Web) 

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    Event date: 2020.11

    Language:Japanese   Presentation type:Oral presentation (general)  

    Venue:Web  

  • 触媒締結構造を持つ強制フローセルによる粉末触媒の酸素発生能評価法

    松浦一生、長澤兼作、黒田義之、光島重徳

    第44回電解技術討論会-ソーダ工業技術討論会-  (Web) 

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    Event date: 2020.11

    Language:Japanese   Presentation type:Oral presentation (general)  

    Venue:Web  

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Charge of on-campus class subject 【 display / non-display

  • 2021   エネルギー先端創生実習F

    Graduate school of Engineering Science

  • 2021   エネルギー先端創生実習S

    Graduate school of Engineering Science

  • 2021   創エネルギー工学技術創生実習F

    Graduate school of Engineering Science

  • 2021   創エネルギー工学技術創生実習S

    Graduate school of Engineering Science

  • 2021   創エネルギー解析実習F

    Graduate school of Engineering Science

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Committee Memberships 【 display / non-display

  • 電気化学会

    2019.4 - 2021.3  理事・会計理事

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    Committee type:Academic society 

    H31-32年度電気化学会理事・会計理事

  • 水素エネルギー協会

    2018.4  業務執行副会長

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    Committee type:Academic society 

  • Electrocatalysis

    2018.1  Topical Editor

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    Committee type:Academic society 

  • 埼玉県 水素エネルギー普及推進協議会

    2017.12  会長

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    Committee type:Other 

  • あおもりCO₂フリー水素検討会

    2016.8 - 2018.3  会長

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    Committee type:Other 

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Social Contribution(Extension lecture) 【 display / non-display

  • 光島重徳「市内CO2排出削減が日本全体に役に立つ」 川崎区で「水素戦略」シンポジウム

    Role(s): Guest, Lecturer, Logistic support

    川崎臨海部水素ネットワーク協議会  「水素戦略」シンポジウムを開催後(川崎区 2020年2月19日)東京新聞に掲載(2020年2月20日)  2020.2

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    Audience: University students, Graduate students, Teachers, Researchers, Company, Government agency, Media, Other

    Type:Lecture

  • エネルギー・環境問題と水素・燃料電池技術の現状

    工学研究院  横浜国立大学  2007.6

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    Type:Extension Lecture

    エネルギー・環境問題を克服し、持続成長可能な社会を築くためには地球規模の視点での問題提起とナノレベルの技術開発が欠かせません。本講座では、来るべき水素社会の本質と新エネルギーの開発、燃料電池の現状技術